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Most people would say he could not because he was not a shapeshifter when he first saw her, as a little kid or on First Beach. But in Sam's story, when he imprinted on Emily, it was said that he had seen her before, but when he became a shapeshifter and saw her again, he imprinted. Jacob did not imprint on Bella once he saw her after he joined the cult in "New Moon" simply because she was not "the one".

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